Uehara Ayumi, Akiyama Shinobu, Iwashina Tsukasa
Nat Prod Commun. 2015 Mar;10(3):403-5.
Foliar flavonoids of Tanacetum vulgare var. boreale were isolated. Eight flavonoid glycosides, 7-O-glucosides of apigenin, luteolin, scutellarein and 6- hydroxyluteolin, and 7-O-glucuronides of apigenin, luteolin, chrysoeriol and eriodictyol were identified. Moreover, eight flavonoid aglycones, apigenin, luteolin, hispidulin, nepetin, eupatilin, jaceosidin, pectolinarigenin and axillarin were also isolated and identified. The flavonoid composition of two varieties of T. vulgare, i.e. var. boreale and var. vulgare, were compared. All samples of var. boreale and one sample of var. vulgare had the same flavonoid pattern, and could be distinguished from almost all the samples of var. vulgare. Thus, the occurrence of chemotypes, which are characterized by either the presence or absence of scutellarein 7-O-glucoside, eriodictyol 7-O-glucuronide and pectolinarigenin was shown in T. vulgare sensu lato.
北艾(Tanacetum vulgare var. boreale)的叶黄酮被分离出来。鉴定出了8种黄酮苷,即芹菜素、木犀草素、黄芩素和6-羟基木犀草素的7-O-葡萄糖苷,以及芹菜素、木犀草素、 Chrysoeriol和圣草酚的7-O-葡萄糖醛酸苷。此外,还分离并鉴定出了8种黄酮苷元,即芹菜素、木犀草素、毛地黄黄酮、尼泊尔黄酮、泽兰黄素、红矢车菊素、果胶类黄酮元及腋生苷。对北艾的两个变种,即北艾变种和普通艾变种的黄酮类成分进行了比较。北艾变种的所有样品和普通艾变种的一个样品具有相同的黄酮类模式,并且可以与普通艾变种的几乎所有样品区分开来。因此,在广义的北艾中显示出了化学型的存在,其特征是存在或不存在黄芩素7-O-葡萄糖苷、圣草酚7-O-葡萄糖醛酸苷和果胶类黄酮元。