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[朔州市PM2.5中有机碳和元素碳的特征]

[Characteristics of organic carbon and elemental carbon in PM2.5 in Shuozhou City].

作者信息

Liu Feng-xian, Peng Lin, Bai Hui-ling, Mu Ling, Liu Xiao-feng, Li Li-juan, Liu Xin

出版信息

Huan Jing Ke Xue. 2015 Mar;36(3):787-93.

Abstract

PM2.5 samples were collected at four sampling sites in Shuozhou during the heating and non-heating periods. Organic carbon (OC) and elemental carbon (EC) in PM2.5 were analyzed by Elementar Analysensysteme GmbH vario EL cube and the concentration, spatial and temporal distribution characteristics and main sources of OC and EC were studied. The results were as following: average concentrations of OC and EC in PM2.5 during non-heating period were (14.3 ± 2.7) μg x m(-3) and (10.3 ± 3.1) μg x m(-3) while (23.3 ± 5.9) μg xm(-3) and (20.0 ± 5.7) μg x m(-3) during heating period. The concentrations of OC and EC at four sites during the heating period were higher than those during the non-heating period. The concentrations of OC and EC at SW site during heating were the highest which were 28.5 μg x m(-3) and 28.1 μg x m(-3) while the concentrations at PS sites during non-heating period were the highest, which were 17.7 μg x m(-3) and 14.1 μg x m(-3). The ratios between OC and EC during the heating and non-heating period were all below 2 and the correlation between OC and EC was not good with R2 of 0. 66 during heating period and 0.52 during non-heating period which indicated that sources of carbon aerosols were complex. Carbonaceous aerosol pollution should be reduced by controlling the primary emissions such as coal combustion, vehicle exhaust and biomass burning, and by paying attention to secondary pollution at the same time to improve the air quality in Shuozhou City. The concentrations of SOC during heating and non-heating period were (6.44 ± 2.77) μg x m(-3) and (4.11 ± 1.92) μg x m(-3).

摘要

在供暖期和非供暖期,于朔州的四个采样点采集了细颗粒物(PM2.5)样本。采用Elementar Analysensysteme GmbH公司的vario EL cube对PM2.5中的有机碳(OC)和元素碳(EC)进行分析,并研究了OC和EC的浓度、时空分布特征及主要来源。结果如下:非供暖期PM2.5中OC和EC的平均浓度分别为(14.3±2.7)μg·m⁻³和(10.3±3.1)μg·m⁻³,而供暖期分别为(23.3±5.9)μg·m⁻³和(20.0±5.7)μg·m⁻³。供暖期四个采样点的OC和EC浓度均高于非供暖期。供暖期西南(SW)采样点的OC和EC浓度最高,分别为28.5μg·m⁻³和28.1μg·m⁻³;非供暖期PS采样点的OC和EC浓度最高,分别为17.7μg·m⁻³和14.1μg·m⁻³。供暖期和非供暖期OC与EC的比值均低于2,且OC与EC的相关性较差,供暖期R²为0.66,非供暖期为0.52,这表明碳气溶胶的来源复杂。应通过控制煤炭燃烧、机动车尾气和生物质燃烧等一次排放,同时关注二次污染,以减少碳质气溶胶污染,改善朔州市的空气质量。供暖期和非供暖期的二次有机碳(SOC)浓度分别为(6.44±2.77)μg·m⁻³和(4.11±1.92)μg·m⁻³。

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