Jin Shu-Lan, Huang Yi-Zong, Wang Fei, Xu Feng, Wang Xiao-Ling, Gao Zhu, Hu Ying, Li Jin, Xiang Meng
Huan Jing Ke Xue. 2015 Mar;36(3):1060-8.
Rare earth elements content in farmland soils and crops of the surrounding copper mining and smelting plant in Jiangxi province was studied. The results showed that copper mining and smelting could increase the content of rare earth elements in soils and crops. Rare earth elements content in farmland soils of the surrounding Yinshan Lead Zinc Copper Mine and Guixi Smelting Plant varied from 112.42 to 397.02 mg x kg(-1) and 48.81 to 250.06 mg x kg(-1), and the average content was 254.84 mg x kg(-1) and 144.21 mg x kg(-1), respectively. The average contents of rare earth elements in soils in these two areas were 1.21 times and 0.68 times of the background value in Jiangxi province, 1.36 times and 0.77 times of the domestic background value, 3.59 times and 2.03 times of the control samples, respectively. Rare earth elements content in 10 crops of the surrounding Guixi Smelting Plant varied from 0.35 to 2.87 mg x kg(-1). The contents of rare earth elements in the leaves of crops were higher than those in stem and root. The contents of rare earth elements in Tomato, lettuce leaves and radish leaves were respectively 2.87 mg x kg(-1), 1.58 mg x kg(-1) and 0.80 mg x kg(-1), which were well above the hygienic standard limit of rare earth elements in vegetables and fruits (0.70 mg x kg(-1)). According to the health risk assessment method recommended by America Environmental Protection Bureau (USEPA), we found that the residents' lifelong average daily intake of rare earth elements was 17.72 mg x (kg x d)(-1), lower than the critical value of rare earth elements damage to human health. The results suggested that people must pay attention to the impact of rare earth elements on the surrounding environment when they mine and smelt copper ore in Jiangxi.
对江西某铜矿山及冶炼厂周边农田土壤和农作物中稀土元素含量进行了研究。结果表明,铜矿山及冶炼活动可使土壤和农作物中稀土元素含量增加。银山铅锌铜矿及贵溪冶炼厂周边农田土壤中稀土元素含量分别为112.42~397.02mg·kg⁻¹和48.81~250.06mg·kg⁻¹,平均含量分别为254.84mg·kg⁻¹和144.21mg·kg⁻¹。这两个区域土壤中稀土元素平均含量分别是江西省背景值的1.21倍和0.68倍,全国背景值的1.36倍和0.77倍,对照样的3.59倍和2.03倍。贵溪冶炼厂周边10种农作物中稀土元素含量为0.35~2.87mg·kg⁻¹。农作物叶片中稀土元素含量高于茎和根。番茄、莴苣叶和萝卜叶中稀土元素含量分别为2.87mg·kg⁻¹、1.58mg·kg⁻¹和0.80mg·kg⁻¹,均远高于蔬菜水果中稀土元素卫生标准限量(0.70mg·kg⁻¹)。采用美国环境保护局(USEPA)推荐的健康风险评价方法,得出居民对稀土元素的终生平均日摄入量为17.72mg·(kg·d)⁻¹,低于稀土元素对人体健康产生损害的临界值。结果提示,江西在进行铜矿石开采和冶炼时必须关注稀土元素对周边环境的影响。