溶剂诱导的立方、球形和蜂窝状钯 N-杂环卡宾颗粒的简便合成及其在氰硅烷化反应中的催化应用。
Solvent-Induced Facile Synthesis of Cubic-, Spherical-, and Honeycomb-Shape Palladium N-Heterocyclic Carbene Particles and Catalytic Applications in Cyanosilylation.
机构信息
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.
University of Chinese Academy of Sciences, Beijing, 100049, China.
出版信息
Small. 2015 Aug 12;11(30):3642-7. doi: 10.1002/smll.201500658. Epub 2015 Apr 30.
The facile synthesis of palladium N-heterocyclic carbene (NHC) particles with spherical, cubic, and honeycomb morphologies is accomplished. The structures of cubic and honeycomb particles are defined as an unprecedented trinuclear palladium-NHC complex. An obvious effect of particle morphologies on catalytic activity and recyclability is observed in hetero-geneous cyanosilylation.
容易地合成了具有球形、立方和蜂窝形态的钯 N-杂环卡宾（NHC）颗粒。立方和蜂窝颗粒的结构被定义为一种前所未有的三核钯-NHC 配合物。在异质氰硅烷化反应中，观察到颗粒形态对催化活性和可回收性的明显影响。
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