在钛硅分子筛中构建具有有机胺配体的独特六配位钛物种及其前所未有的烯烃环氧化高效性。
Construction of unique six-coordinated titanium species with an organic amine ligand in titanosilicate and their unprecedented high efficiency for alkene epoxidation.
作者信息
Xu Le, Huang Da-Ding, Li Chen-Geng, Ji Xinyi, Jin Shaoqing, Feng Zhaochi, Xia Fei, Li Xiaohong, Fan Fengtao, Li Can, Wu Peng
机构信息
Shanghai Key Lab of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai, 200062, China.
出版信息
Chem Commun (Camb). 2015 May 28;51(43):9010-3. doi: 10.1039/c5cc02321a.
PMID:25939308
Abstract
A novel organic-inorganic layered titanosilicate consisting of Ti-containing MWW-type nanosheets and piperidine ligands was constructed. It exhibited an unprecedented high catalytic activity and recyclability in alkene epoxidation.
摘要
构建了一种由含钛MWW型纳米片和哌啶配体组成的新型有机-无机层状钛硅酸盐。它在烯烃环氧化反应中表现出前所未有的高催化活性和可循环性。
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