通过开环易位聚合制备的聚（亚芳基乙烯撑）供体-受体共轭嵌段共聚物。
A donor-acceptor conjugated block copolymer of poly(arylenevinylene)s by ring-opening metathesis polymerization.
作者信息
Chang Shu-Wei, Horie Masaki
机构信息
Department of Chemical Engineering, National Tsing-Hua University, 101, Section 2, Kuang-Fu Road, Hsinchu, 30013 Taiwan.
出版信息
Chem Commun (Camb). 2015 Jun 4;51(44):9113-6. doi: 10.1039/c5cc00498e.
Novel conjugated cyclophanes comprising electron donating cyclopentadithiophene-vinylene and accepting dithienobenzothiadiazole-vinylene have been synthesized by McMurry coupling. Ring-opening metathesis polymerization (ROMP) of the acceptor monomer and the subsequent addition of the donor monomer allows the preparation of a fully conjugated diblock copolymer. The diblock copolymer exhibits multiple optical and electrochemical functions.
通过麦克默里偶联反应合成了新型共轭环番，其包含供电子的环戊二噻吩-亚乙烯基和吸电子的二噻吩并苯并噻二唑-亚乙烯基。受体单体的开环易位聚合（ROMP）以及随后供体单体的添加使得能够制备完全共轭的二嵌段共聚物。该二嵌段共聚物具有多种光学和电化学功能。
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