羧酸衍生物加氢的多相和均相催化：历史、进展和未来方向。
Heterogeneous and homogeneous catalysis for the hydrogenation of carboxylic acid derivatives: history, advances and future directions.
机构信息
Inorganic Materials Chemistry group, Schuit Institute of Catalysis, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
出版信息
Chem Soc Rev. 2015 Jun 7;44(11):3808-33. doi: 10.1039/c5cs00038f.
The catalytic reduction of carboxylic acid derivatives has witnessed a rapid development in recent years. These reactions, involving molecular hydrogen as the reducing agent, can be promoted by heterogeneous and homogeneous catalysts. The milestone achievements and recent results by both approaches are discussed in this Review. In particular, we focus on the mechanistic aspects of the catalytic hydrogenation and highlight the bifunctional nature of the mechanism that is preferred for supported metal catalysts as well as homogeneous transition metal complexes.
近年来，羧酸衍生物的催化还原反应取得了快速发展。这些反应以氢气作为还原剂，可由多相和均相催化剂来促进。本文综述了这两种方法的里程碑式成就和最新成果。特别地，我们关注催化加氢的机理方面，并强调了负载金属催化剂以及均相过渡金属配合物所倾向的双功能机理的特性。
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