碘催化自由基氧化环化反应构建二氢呋喃和中氮茚。
Iodine-catalyzed radical oxidative annulation for the construction of dihydrofurans and indolizines.
作者信息
Tang Shan, Liu Kun, Long Yue, Gao Xinlong, Gao Meng, Lei Aiwen
机构信息
†College of Chemistry and Molecular Sciences, The Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, People's Republic of China.
‡National Research Center for Carbohydrate Synthesis, Jiangxi Normal University, Nanchang 330022, People's Republic of China.
出版信息
Org Lett. 2015 May 15;17(10):2404-7. doi: 10.1021/acs.orglett.5b00912. Epub 2015 May 6.
Through iodine catalysis, the direct oxidative coupling/annulation of β-keto esters or 2-pyridinyl-β-esters with alkenes was achieved. This reaction procedure provides a simple and selective way for the synthesis of dihydrofurans and indolizines in one step.
通过碘催化，实现了β-酮酯或2-吡啶基-β-酯与烯烃的直接氧化偶联/环化反应。该反应过程为一步合成二氢呋喃和中氮茚提供了一种简单且具有选择性的方法。
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