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厌氧消化与嗜热好氧消化联合工艺中稳定性及污泥性质的影响

Effects of stabilization and sludge properties in a combined process of anaerobic digestion and thermophilic aerobic digestion.

作者信息

Cheng Jiehong, Kong Feng, Zhu Jun, Wu Xiao

机构信息

a School of Chemical and Environmental Engineering , Jiangsu University of Technology , Changzhou 213001 , People's Republic of China.

b Department of Biological and Agricultural Engineering , University of Arkansas , Fayetteville , AR 72701 , USA.

出版信息

Environ Technol. 2015;36(21):2786-95. doi: 10.1080/09593330.2015.1049212. Epub 2015 Jun 4.

Abstract

A novel process of combining mesophilic (<35°C) anaerobic digestion with the thermophilic (55°C) aerobic digestion process (AN-TAD) was designed to stabilize sludge and economize aeration energy. Effects of stabilization and sludge properties for AN-TAD process were evaluated by batch experiments during a 25 d digestion period. The sludges digested by AN-TAD process achieved the requirements for Class-A sludge standard. The sludge at total solid (TS) 5.4% had the highest value of decay coefficient K(d(55)) at 0.1851 d(-1) among the three TS contents according to the first-order kinetics equation. Oxidation reduction potential at below 0 mV remained for sludges at TSs of 6.5%, 5.4%, and 4.6% for at least 15 d because of initial hydrolytic-acidification. Concentrations of nitrogen and phosphorus in sludges at TSs of 6.5%, 5.4%, and 4.6% gradually increased up to the highest values in the supernatant during the initial 13 d, causing low utilized value in land application as a fertilizer. Prolonging the retention time for more than 15 d was considered because soluble phosphorus precipitated in the solid phase. High content of soluble organic matters of the soluble chemical oxygen demand, protein, and polysaccharide in the supernatant caused deterioration in sludge dewaterability rates.

摘要

设计了一种将中温(<35°C)厌氧消化与高温(55°C)好氧消化工艺相结合的新型工艺(AN-TAD),以实现污泥稳定化并节省曝气能源。通过在25天的消化期内进行批次实验,评估了AN-TAD工艺对污泥的稳定化效果和污泥性质。经AN-TAD工艺消化的污泥达到了A级污泥标准的要求。根据一级动力学方程,在三种总固体(TS)含量中,TS为5.4%的污泥具有最高的衰减系数K(d(55)),为0.1851 d(-1)。由于初始水解酸化作用,TS分别为6.5%、5.4%和4.6%的污泥的氧化还原电位在至少15天内保持在0 mV以下。TS为6.5%、5.4%和4.6%的污泥中的氮和磷浓度在最初的13天内逐渐增加至上清液中的最高值,导致其作为肥料在土地应用中的利用价值较低。考虑延长停留时间超过15天,因为可溶性磷会在固相中沉淀。上清液中可溶性化学需氧量、蛋白质和多糖等可溶性有机物含量较高,导致污泥脱水率下降。

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