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基于合理设计的蓝色发光凝胶因子的镧系配位聚合物凝胶中的可调发射。

Tunable emission in lanthanide coordination polymer gels based on a rationally designed blue emissive gelator.

作者信息

Sutar Papri, Suresh Venkata M, Maji Tapas Kumar

机构信息

Molecular Materials Laboratory, Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560 064, India.

出版信息

Chem Commun (Camb). 2015 Jun 18;51(48):9876-9. doi: 10.1039/c5cc02709h.

DOI:10.1039/c5cc02709h
PMID:25995095
Abstract

Rational design and synthesis of a new low molecular weight gelator (LMWG) having 9,10-diphenylanthracene core and terminal terpyridine is reported. Tb(III) and Eu(III) ion coordination to a LMWG results in green and pink emissive coordination polymer gels, respectively, with coiled nanofiber morphology. Further, control over stoichiometry of LMWG:Tb(III):Eu(III) leads to yellow and white light emitting bimetallic gels.

摘要

报道了一种具有9,10 - 二苯基蒽核心和末端三联吡啶的新型低分子量凝胶剂(LMWG)的合理设计与合成。Tb(III)和Eu(III)离子与LMWG配位分别产生绿色和粉红色发光的配位聚合物凝胶,具有卷曲的纳米纤维形态。此外,控制LMWG:Tb(III):Eu(III)的化学计量比可得到黄色和白色发光的双金属凝胶。

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