Ben Rhaiem Tarek, Boughzala Habib
Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 Manar II Tunis, Tunisia.
Acta Crystallogr E Crystallogr Commun. 2015 Apr 18;71(Pt 5):498-501. doi: 10.1107/S2056989015007379. eCollection 2015 May 1.
The hybrid title compound, catena-poly[[[bis-(1,4-diazo-niabi-cyclo-[2.2.2]octa-ne) [tetra-achlorido-anti-monate(III)]-μ-chlorido-[tetra-chlorido-anti-monate(III)]-μ-chlorido]] monohydrate], {(C6H14N2)2[Sb2Cl10]·H2O} n , is self-assembled into alternating organic and inorganic layers parallel to the bc plane. The anionic inorganic layer consists of infinite zigzag chains of corner-sharing SbCl6 octa-hedra running along the b axis. The organic part is made up of 1,4-diazo-niabi-cyclo-[2.2.2]octane dications (dabcoH2 (2+)). The water mol-ecules in the structure connect inorganic and organic layers. Hydrogen-bonding inter-actions between the ammonium groups, water mol-ecules and Cl atoms ensure the structure cohesion.
杂化标题化合物，链状聚[[[双-(1,4-二氮杂双环-[2.2.2]辛烷)[四氯合锑(III)]-μ-氯-[四氯合锑(III)]-μ-氯]]一水合物]，{(C₆H₁₄N₂)₂[Sb₂Cl₁₀]·H₂O}ₙ，自组装成平行于bc平面的交替有机和无机层。阴离子无机层由沿b轴延伸的角共享SbCl₆八面体的无限之字形链组成。有机部分由1,4-二氮杂双环-[2.2.2]辛烷二价阳离子（达布寇H₂(²⁺)）组成。结构中的水分子连接无机层和有机层。铵基、水分子和Cl原子之间的氢键相互作用确保了结构的凝聚性。
