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碳纳米片:合成与应用。

Carbon Nanosheets: Synthesis and Application.

机构信息

State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, Shanxi, 030001 (P.R. China), Fax: (+86) 351-4041153.

University of Chinese Academy of Sciences, Beijing, 100049 (P.R. China).

出版信息

ChemSusChem. 2015 Jun 22;8(12):2004-27. doi: 10.1002/cssc.201500141. Epub 2015 Jun 3.

Abstract

Carbon nanosheets (CNSs) with tunable sizes, morphologies, and pore structures have been synthesized through several chemical routes. Graphitized CNSs have been synthesized through exfoliation, chemical vapor deposition, or high-temperature carbonization. Porous CNSs have been synthesized by using various methods, including pyrolysis, self-assembly, or a solvothermal method in connection with carbonization. These CNSs have successfully been used as detectors for metal ions, as cathodes for field electron emissions, as electrodes for supercapacitors and fuel cells, and as supports for photocatalytic and catalytic oxygen reduction. Therefore, the synthesis and application of CNSs are receiving increasing levels of interest, particularly as application benefits, in the context of future energy/chemical industry, are becoming recognized. This review provides a summary of the most recent and important progress in the production of CNSs and highlights their application in environmental and energy-related fields.

摘要

碳纳米片(CNSs)具有可调节的尺寸、形态和孔结构,可通过多种化学途径合成。石墨化 CNSs 可通过剥离、化学气相沉积或高温碳化合成。多孔 CNSs 可通过各种方法合成,包括热解、自组装或与碳化相关的溶剂热法。这些 CNSs 已成功用作金属离子的探测器、场电子发射的阴极、超级电容器和燃料电池的电极、以及光催化和催化氧气还原的载体。因此,CNSs 的合成和应用越来越受到关注,特别是随着未来能源/化学工业的应用效益逐渐得到认可。本文综述了 CNSs 生产的最新和重要进展,并重点介绍了它们在环境和能源相关领域的应用。

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