在p型半导体NiO电极上使用Ru(II)-Re(I)多核金属配合物进行光电化学CO₂还原。
Photoelectrochemical CO2 reduction using a Ru(II)-Re(I) multinuclear metal complex on a p-type semiconducting NiO electrode.
作者信息
Sahara Go, Abe Ryu, Higashi Masanobu, Morikawa Takeshi, Maeda Kazuhiko, Ueda Yutaro, Ishitani Osamu
机构信息
Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama 2-12-1-NE-1, Meguro-ku, Tokyo 152-8550, Japan.
出版信息
Chem Commun (Camb). 2015 Jul 7;51(53):10722-5. doi: 10.1039/c5cc02403j.
A photocathode for CO2 reduction was successfully developed using a hybrid electrode comprising a Ru(II)-Re(I) supramolecular photocatalyst and a NiO electrode. Selective photoexcitation of the Ru photosensitizer unit of the photocatalyst at -1.2 V vs. Ag/AgNO3 selectively afforded CO with high faradaic efficiency.
通过使用由钌（II）-铼（I）超分子光催化剂和氧化镍电极组成的混合电极，成功开发出一种用于二氧化碳还原的光阴极。相对于银/硝酸银，在-1.2 V下对光催化剂的钌光敏剂单元进行选择性光激发，以高法拉第效率选择性地生成一氧化碳。
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