Sahara Go, Abe Ryu, Higashi Masanobu, Morikawa Takeshi, Maeda Kazuhiko, Ueda Yutaro, Ishitani Osamu
Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama 2-12-1-NE-1, Meguro-ku, Tokyo 152-8550, Japan.
Chem Commun (Camb). 2015 Jul 7;51(53):10722-5. doi: 10.1039/c5cc02403j.
A photocathode for CO2 reduction was successfully developed using a hybrid electrode comprising a Ru(II)-Re(I) supramolecular photocatalyst and a NiO electrode. Selective photoexcitation of the Ru photosensitizer unit of the photocatalyst at -1.2 V vs. Ag/AgNO3 selectively afforded CO with high faradaic efficiency.
通过使用由钌（II）-铼（I）超分子光催化剂和氧化镍电极组成的混合电极，成功开发出一种用于二氧化碳还原的光阴极。相对于银/硝酸银，在-1.2 V下对光催化剂的钌光敏剂单元进行选择性光激发，以高法拉第效率选择性地生成一氧化碳。
