Civil and Environmental Engineering Department, Virginia Tech, Durham Hall 418, Blacksburg, Virginia 24061, United States.
Environ Sci Technol. 2015 Jul 21;49(14):8697-703. doi: 10.1021/acs.est.5b01824. Epub 2015 Jun 26.
Copper and iron pipes have a remarkable capability for autogenous repair (self-repair) of leaks in potable water systems. Field studies revealed exemplars that metallic pipe leaks caused by nails, rocks, and erosion corrosion autogenously repaired, as confirmed in the laboratory experiments. This work demonstrated that 100% (N = 26) of 150 μm leaks contacting representative bulk potable water in copper pipes sealed autogenously via formation of corrosion precipitates at 20-40 psi, pH 3.0-11.0, and with upward and downward leak orientations. Similar leaks in carbon steel pipes at 20 psi self-repaired at pH 5.5 and 8.5, but two leaks did not self-repair permanently at pH 11.0 suggesting that water chemistry may control the durability of materials that seal the leaks and therefore the permanence of repair. Larger 400 μm holes in copper pipes had much lower (0-33%) success of self-repair at pH 3.0-11.0, whereas all 400 μm holes in carbon steel pipes at 20 psi self-repaired at pH 4.0-11.0. Pressure tests indicated that some of the repairs created at 20-40 psi ambient pressure could withstand more than 100 psi without failure. Autogenous repair has implications for understanding patterns of pipe failures, extending the lifetime of decaying infrastructure, and developing new plumbing materials.
铜质和铁质管道对于饮用水系统的渗漏具有显著的自修复(自我修复)能力。现场研究揭示了一些实例,即由于钉子、岩石和侵蚀腐蚀导致的金属管道泄漏可以自行修复,这在实验室实验中得到了证实。这项工作表明,在 20-40 psi、pH 值 3.0-11.0 以及向上和向下泄漏方向的情况下,接触代表性散装饮用水的 150 μm 泄漏(N = 26)在铜质管道中通过腐蚀沉淀物的形成而自行密封的比例为 100%。在 20 psi 下,类似的碳钢管道泄漏在 pH 值为 5.5 和 8.5 时可以自行修复,但在 pH 值为 11.0 时有两个泄漏无法永久自行修复,这表明水化学可能会控制密封泄漏的材料的耐久性,从而影响修复的持久性。在 pH 值为 3.0-11.0 的情况下,铜质管道中 400 μm 的较大孔的自修复成功率要低得多(0-33%),而在 20 psi 下,所有 400 μm 的碳钢管道泄漏在 pH 值为 4.0-11.0 时都可以自行修复。压力测试表明,在 20-40 psi 环境压力下创建的一些修复可以在不失效的情况下承受超过 100 psi 的压力。自修复对于理解管道故障模式、延长老化基础设施的使用寿命以及开发新型管道材料具有重要意义。