通过二甲基硅醇基团的氢键作用实现笼型硅氧烷的规则组装。
Regular assembly of cage siloxanes by hydrogen bonding of dimethylsilanol groups.
作者信息
Sato Naoto, Kuroda Yoshiyuki, Abe Takuya, Wada Hiroaki, Shimojima Atsushi, Kuroda Kazuyuki
机构信息
Department of Applied Chemistry, Faculty of Science and Engineering, Waseda University, 3-4-1 Ohkubo, Shinjuku-ku, Tokyo 169-8555, Japan.
出版信息
Chem Commun (Camb). 2015 Jul 14;51(55):11034-7. doi: 10.1039/c5cc03668b.
PMID:26063451
Abstract
A new class of ordered silica-based materials has been prepared by hydrogen bond-directed assembly of cage siloxanes modified with dimethylsilanol groups, providing a soft-chemical approach to crystalline silica materials with molecularly designed architectures.
摘要
通过氢键导向组装用二甲基硅醇基团修饰的笼型硅氧烷，制备了一类新型的有序硅基材料，为具有分子设计结构的结晶二氧化硅材料提供了一种软化学方法。
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