Pei Y H, Li X, Zhu T R
Yao Xue Xue Bao. 1989;24(6):413-21.
Fourteen new compounds were synthesized of which twelve are (S)-(+)-alpha-methylbutyrylphloroglucinols. On the basis of optical rotation data and theoretical analysis, an empirical correlation between optical rotation and absolute configuration of optically active alpha-methylbutyrylphloroglucinols has been established by means of Brewster's rule of atomic asymmetry. It can be served as a means of absolute configuration assignment of optically active alpha-methylbutyrylphloroglucinols.
合成了14种新化合物，其中12种是(S)-(+)-α-甲基丁酰间苯三酚。基于旋光数据和理论分析，借助布鲁斯特原子不对称规则建立了旋光性α-甲基丁酰间苯三酚的旋光度与绝对构型之间的经验相关性。它可作为确定旋光性α-甲基丁酰间苯三酚绝对构型的一种方法。
