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热处理不锈钢毡作为可扩展的生物电化学系统阳极材料。

Heat-treated stainless steel felt as scalable anode material for bioelectrochemical systems.

机构信息

Laboratory of Microbial Ecology and Technology, Ghent University, Coupure Links 653, B-9000 Ghent, Belgium.

School of Chemistry, University of New South Wales, Sydney, NSW 2052, Australia.

出版信息

Bioresour Technol. 2015 Nov;195:46-50. doi: 10.1016/j.biortech.2015.06.060. Epub 2015 Jun 18.

Abstract

This work reports a simple and scalable method to convert stainless steel (SS) felt into an effective anode for bioelectrochemical systems (BESs) by means of heat treatment. X-ray photoelectron spectroscopy and cyclic voltammetry elucidated that the heat treatment generated an iron oxide rich layer on the SS felt surface. The iron oxide layer dramatically enhanced the electroactive biofilm formation on SS felt surface in BESs. Consequently, the sustained current densities achieved on the treated electrodes (1 cm(2)) were around 1.5±0.13 mA/cm(2), which was seven times higher than the untreated electrodes (0.22±0.04 mA/cm(2)). To test the scalability of this material, the heat-treated SS felt was scaled up to 150 cm(2) and similar current density (1.5 mA/cm(2)) was achieved on the larger electrode. The low cost, straightforwardness of the treatment, high conductivity and high bioelectrocatalytic performance make heat-treated SS felt a scalable anodic material for BESs.

摘要

这项工作报道了一种简单且可扩展的方法,通过热处理将不锈钢(SS)毛毡转化为生物电化学系统(BES)的有效阳极。X 射线光电子能谱和循环伏安法表明,热处理在 SS 毛毡表面产生了富含氧化铁的层。氧化铁层在 BES 中极大地促进了 SS 毛毡表面上的电活性生物膜的形成。因此,处理后的电极(1 cm(2))上获得的持续电流密度约为 1.5±0.13 mA/cm(2),是未处理电极(0.22±0.04 mA/cm(2))的七倍。为了测试这种材料的可扩展性,将热处理后的 SS 毛毡扩大到 150 cm(2),并且在更大的电极上获得了类似的电流密度(1.5 mA/cm(2))。这种材料具有低成本、处理简单、高导电性和高生物电催化性能,使其成为适用于 BES 的可扩展阳极材料。

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