Unique binding behaviour of water-soluble polycationic oxacalix[4]arene tweezers towards the paraquat dication.

作者信息

Manganaro Nadia, Lando Gabriele, Gargiulli Claudia, Pisagatti Ilenia, Notti Anna, Pappalardo Sebastiano, Parisi Melchiorre F, Gattuso Giuseppe

机构信息

Dipartimento di Scienze Chimiche, Università di Messina, viale F. Stagno d'Alcontres 31, 98166 Messina, Italy.

出版信息

Chem Commun (Camb). 2015 Aug 14;51(63):12657-60. doi: 10.1039/c5cc04079e.

DOI:10.1039/c5cc04079e

PMID:26160455

Abstract

The first water-soluble polycationic oxacalix[4]arene molecular tweezers able to recognize - under pH control - the paraquat dication as a result of a delicate balance between electrostatic repulsion, Coulombic shielding and attractive π-stacking interactions are reported.

摘要