Larrañaga Miren, Bou-Ali M Mounir, Lizarraga Ion, Madariaga Jose Antonio, Santamaría Carlos
MGEP Mondragon Goi Eskola Politeknikoa, Mechanical and Industrial Manufacturing Department, Loramendi 4 Apdo. 23, 20500 Mondragon, Spain.
Department of Applied Physics II, University of Basque Country, Apdo. 644, 48080 Bilbao, Spain.
J Chem Phys. 2015 Jul 14;143(2):024202. doi: 10.1063/1.4926654.
In this work, the transport coefficients of the ternary mixtures of the diffusion coefficient measurements in ternary mixtures 1 project were determined. The analyzed ternary mixtures are formed by 1,2,3,4-tetrahydronaphthalene, isobutylbenzene, and dodecane (nC12) at different compositions. In all cases, the analysis was carried out at 25 °C. The thermodiffusion coefficients were measured by a new thermogravitational column, and the molecular diffusion coefficients were determined by the sliding symmetric tubes technique. Finally, the Soret coefficients were ascertained from the measurements of the thermodiffusion and molecular diffusion coefficients. In addition, two new quantitative correlations which enable the prediction of the thermodiffusion and Soret coefficients of a ternary mixture are presented. The comparison between the experimental and the predicted data shows a good agreement. The presented results help to complete the lack of experimental data in ternary mixtures. In addition, this work improves the fundamental understanding of multicomponent mixtures.
在这项工作中,测定了三元混合物1项目中三元混合物扩散系数测量的传输系数。所分析的三元混合物由1,2,3,4-四氢萘、异丁基苯和不同组成的十二烷(正十二烷)形成。在所有情况下,分析均在25℃下进行。用新型热重力柱测量热扩散系数,并用滑动对称管技术测定分子扩散系数。最后,根据热扩散系数和分子扩散系数的测量结果确定索雷特系数。此外,还提出了两个新的定量关联式,用于预测三元混合物的热扩散系数和索雷特系数。实验数据与预测数据的比较显示出良好的一致性。所呈现的结果有助于填补三元混合物实验数据的空白。此外,这项工作增进了对多组分混合物的基本理解。