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对三元混合物基准的贡献:通过热重力法和滑动对称管技术测定索雷特系数。

Contribution to the benchmark for ternary mixtures: Determination of Soret coefficients by the thermogravitational and the sliding symmetric tubes techniques.

作者信息

Larrañaga Miren, Bou-Ali M Mounir, de Mezquıa David Alonso, Rees D Andrew S, Madariaga Jose Antonio, Santamaría Carlos, Platten Jean K

机构信息

Mechanical and Industrial Manufacturing Department, MGEP Mondragon Goi Eskola Politeknikoa, Loramendi 4 Apdo 23, 20500, Mondragon, Spain.

出版信息

Eur Phys J E Soft Matter. 2015 Apr;38(4):28. doi: 10.1140/epje/i2015-15028-1. Epub 2015 Apr 28.

DOI:10.1140/epje/i2015-15028-1
PMID:25916234
Abstract

This work is part of an international project for the research on the transport properties in ternary mixtures. Six different teams have analysed the same mixture by independent techniques in order to compare the results and validate the techniques. This work is the contribution of the team of Mondragon Unibertsitatea for ground conditions measurements. This team has measured the thermodiffusion coefficients by the thermogravitational techniques and the molecular diffusion coefficients by the Sliding Symmetric Tubes technique. The Soret coefficients have been determined by the combination of the thermodiffusion and molecular diffusion coefficients. The mixture chosen for the study is the one formed by 1,2,3,4-tetrahydronaphtalene, isobutylbenzene and n-dodecane at mass fraction of 80% of THN, 10% of IBB and 10% of n C12, and at 25°C. The good agreement between the results of the different teams shows the validity of the techniques used in this work.

摘要

这项工作是一个关于三元混合物传输特性研究的国际项目的一部分。六个不同的团队通过独立技术分析了同一混合物,以便比较结果并验证这些技术。这项工作是蒙德拉贡大学团队在地面条件测量方面的贡献。该团队通过热重力技术测量了热扩散系数,并通过滑动对称管技术测量了分子扩散系数。索雷特系数是通过热扩散系数和分子扩散系数的组合确定的。用于该研究的混合物是由1,2,3,4 - 四氢萘、异丁基苯和正十二烷组成,质量分数分别为80%的THN、10%的IBB和10%的正十二烷,温度为25°C。不同团队的结果之间的良好一致性表明了本工作中所使用技术的有效性。

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本文引用的文献

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J Chem Phys. 2014 Feb 7;140(5):054201. doi: 10.1063/1.4864189.
2
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J Chem Phys. 2013 Sep 14;139(10):104903. doi: 10.1063/1.4820357.
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Communication: New approach for analysis of thermodiffusion coefficients in ternary mixtures.
Eur Phys J E Soft Matter. 2019 Mar 7;42(3):27. doi: 10.1140/epje/i2019-11789-7.
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Editorial: Thermal non-equilibrium phenomena in multi-component fluids.社论:多组分流体中的热非平衡现象
Eur Phys J E Soft Matter. 2015 Apr;38(4):31. doi: 10.1140/epje/i2015-15031-6. Epub 2015 Apr 29.
交流:三元混合物中热扩散系数分析的新方法。
J Chem Phys. 2013 Apr 28;138(16):161102. doi: 10.1063/1.4802987.
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A comprehensive study of diffusion, thermodiffusion, and Soret coefficients of water-isopropanol mixtures.水-异丙醇混合物的扩散、热扩散和 Soret 系数的综合研究。
J Chem Phys. 2012 Jun 28;136(24):244512. doi: 10.1063/1.4730306.
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Determination of molecular diffusion coefficient in n-alkane binary mixtures: empirical correlations.测定正烷烃二元混合物中的分子扩散系数:经验关联。
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