Datta Sougata, Bhattacharya Santanu
Department of Organic Chemistry, Indian Institute of Science, Bangalore, India.
Chem Commun (Camb). 2015 Sep 21;51(73):13929-32. doi: 10.1039/c5cc05367f.
A new chiral amphiphilic salicylideneaniline bearing a terminal pyridine was synthesized. It formed reverse vesicles in toluene. The addition of Ag(+), however, reversibly transforms these reverse vesicles into left-handed nanohelices accompanied by spontaneous gel formation at room temperature.
合成了一种带有末端吡啶的新型手性两亲性水杨醛苯胺。它在甲苯中形成反相囊泡。然而,加入Ag(+)后,这些反相囊泡在室温下可逆地转变为左手纳米螺旋,并伴随自发凝胶形成。