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利用辐照和水热处理诱导的纳米网络降低农药的污染风险。

Reducing the pollution risk of pesticide using nano networks induced by irradiation and hydrothermal treatment.

作者信息

Sun Xiao, Liu Zuojun, Zhang Guilong, Qiu Guannan, Zhong Naiqin, Wu Lifang, Cai Dongqing, Wu Zhengyan

机构信息

a Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province , Hefei , P. R. China.

b Bioenergy Forest Research Centre of State Forestry Administration , Hefei , P. R. China.

出版信息

J Environ Sci Health B. 2015;50(12):901-7. doi: 10.1080/03601234.2015.1067097. Epub 2015 Aug 12.

Abstract

Traditional pesticides (TP) often do not adhere tightly to crop foliage. They can easily enter the surrounding environment through precipitation and volatilization. This can result in the pollution of the surrounding soil, water, and air. To reduce pesticide pollution, we developed a loss-control pesticide (LCP) by adding attapulgite with a nano networks structure fabricated using high energy electron beam (HEEB) irradiation and hydrothermal treatment to TP. HEEB irradiation effectively dispersed originally aggregated attapulgite through modified thermal, charge, and physical effects. Hydrothermal treatment further enhanced the dispersion of attapulgite to form nano porous networks via thermal and wet expansion effects, which are beneficial for pesticide binding. An LCP has improved retention on crop leaf surfaces. It has a higher adhesion capacity, reduced leaching and volatilization, and extended residual activity compared with the TP formulation. The treatment increases the residual activity of pesticides on crop foliage and decreases environmental pollution.

摘要

传统农药(TP)通常不能紧密附着在作物叶片上。它们很容易通过降水和挥发进入周围环境。这可能导致周围土壤、水和空气的污染。为了减少农药污染,我们通过向TP中添加经高能电子束(HEEB)辐照和水热处理制备的具有纳米网络结构的凹凸棒石,开发了一种控失农药(LCP)。HEEB辐照通过改变热、电荷和物理效应有效地分散了原本聚集的凹凸棒石。水热处理通过热膨胀和湿膨胀效应进一步增强了凹凸棒石的分散性,形成纳米多孔网络,有利于农药结合。LCP在作物叶片表面的滞留性得到改善。与TP制剂相比,它具有更高的粘附能力,减少了淋溶和挥发,并延长了残留活性。该处理增加了农药在作物叶片上的残留活性,减少了环境污染。

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