室温下水中芳基溴化物的还原反应。
Reductions of aryl bromides in water at room temperature.
作者信息
Fennewald James C, Landstrom Evan B, Lipshutz Bruce H
机构信息
Department of Chemistry and Biochemistry, University of California, Santa Barbara 93106 USA.
出版信息
Tetrahedron Lett. 2015 Jun 3;56(23):3608-3611. doi: 10.1016/j.tetlet.2015.02.066.
Abstract
Micellar nanoreactors derived from commercially available 'Nok' (SPGS-550-M), in the presence of Fu's catalyst and a mild hydride source (NaBH), are useful for facile debromination of functionalized aromatic derivatives. This mild and environemntally responsible process is utlized in water at room temperature, and the reaction mixtures can be smoothly recycled.
摘要
源自市售“Nok”（SPGS - 550 - M）的胶束纳米反应器，在傅氏催化剂和温和的氢化物源（NaBH）存在下，可用于功能化芳香族衍生物的简便脱溴反应。这个温和且对环境友好的过程在室温下于水中进行，反应混合物可顺利循环利用。
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