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在间歇式反应器中,以钯/碳催化剂在低压和低温下对马来酸酐进行液相加氢反应。

Liquid Hydrogenation of Maleic Anhydride with Pd/C Catalyst at Low Pressure and Temperature in Batch Reactor.

作者信息

Kim Ji Sun, Baek Jae Ho, Ryu Young Bok, Hong Seong-Soo, Lee Man Sig

出版信息

J Nanosci Nanotechnol. 2015 Jan;15(1):290-4. doi: 10.1166/jnn.2015.8349.

Abstract

Succinic acid (SA) produced from hydrogenation of maleic anhydride (MAN) is used widely in manufacturing of pharmaceuticals, agrochemicals, surfactants and detergent, green solvent and biodegradable plastic. In this study, we performed that liquid hydrogenation of MAN to SA with 5 wt% Pd supported on activated carbon (Pd/C) at low pressure and temperature. The synthesis of SA was performed in aqueous solution while varying temperature, pressure, catalytic amount and agitation speed. We confirmed that the composition of the products consisting of SA, maleic acid (MA), fumaric acid (FA) and malic acid (MLA) depends on the process. The catalytic characteristics were analyzed by TGA, TEM.

摘要

由马来酸酐(MAN)氢化制得的琥珀酸(SA)广泛应用于制药、农用化学品、表面活性剂和洗涤剂、绿色溶剂及可生物降解塑料的生产中。在本研究中,我们在低压和低温条件下,使用负载在活性炭上的5 wt%钯(Pd/C)对MAN进行液相加氢制SA。SA的合成在水溶液中进行,同时改变温度、压力、催化剂量和搅拌速度。我们证实,由SA、马来酸(MA)、富马酸(FA)和苹果酸(MLA)组成的产物组成取决于工艺过程。通过热重分析(TGA)、透射电子显微镜(TEM)对催化特性进行了分析。

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