钯/降冰片烯催化芳基碘的 C-H 酰化反应。
Ortho C-H Acylation of Aryl Iodides by Palladium/Norbornene Catalysis.
机构信息
Department of Chemistry, University of Texas at Austin, 100 East 24th street, Austin, TX 78712 (USA) http://gbdong.cm.utexas.edu/
Department of Chemistry, University of Texas at Austin, 100 East 24th street, Austin, TX 78712 (USA) http://gbdong.cm.utexas.edu/.
出版信息
Angew Chem Int Ed Engl. 2015 Oct 19;54(43):12664-8. doi: 10.1002/anie.201506397. Epub 2015 Sep 1.
PMID:26333071
Abstract
Reported herein is a palladium/norbornene-catalyzed ortho-arene acylation of aryl iodides by a Catellani-type C-H functionalization. This transformation is enabled by isopropyl carbonate anhydrides, which serve as both an acyl cation equivalent and a hydride source.
摘要
本文报道了钯/降冰片烯催化的芳基碘的邻位芳基酰化反应，这是一种 Catellani 型 C-H 官能化反应。这种转化是由碳酸异丙酯酐实现的，它既是酰正离子等价物，也是氢化物源。
Zotero 插件