Tu Charng-Gan, Yao Yu-Feng, Liao Che-Hao, Su Chia-Ying, Hsieh Chieh, Weng Chi-Ming, Lin Chun-Han, Chen Hao-Tsung, Kiang Yean-Woei, Yang C C
Opt Express. 2015 Aug 24;23(17):21919-30. doi: 10.1364/OE.23.021919.
The growth of a two-section, core-shell, InGaN/GaN quantum-well (QW) nanorod- (NR-) array light-emitting diode device based on a pulsed growth technique with metalorganic chemical vapor deposition is demonstrated. A two-section n-GaN NR is grown through a tapering process for forming two uniform NR sections of different cross-sectional sizes. The cathodoluminescence (CL), photoluminescence (PL), and electrolumines-cence (EL) characterization results of the two-section NR structure are compared with those of a single-section NR sample, which is prepared under the similar condition to that for the first uniform NR section of the two-section sample. All the CL, PL, and EL spectra of the two-section sample (peaked between 520 and 525 nm) are red-shifted from those of the single-section sample (peaked around 490 nm) by >30 nm in wavelength. Also, the emitted spectral widths of the two-section sample become significantly larger than their counterparts of the single-section sample. The PL spectral full-width at half-maximum increases from ~37 to ~61 nm. Such variations are attributed to the higher indium incorporation in the sidewall QWs of the two-section sample due to the stronger strain relaxation in an NR section of a smaller cross-sectional size and the more constituent atom supply from the larger gap volume between neighboring NRs.
展示了一种基于脉冲生长技术和金属有机化学气相沉积法生长的两段式、核壳结构、氮化铟镓/氮化镓量子阱(QW)纳米棒(NR)阵列发光二极管器件。通过渐变工艺生长两段式n型氮化镓纳米棒,以形成两个具有不同横截面尺寸的均匀纳米棒段。将两段式纳米棒结构的阴极发光(CL)、光致发光(PL)和电致发光(EL)表征结果与单段式纳米棒样品的结果进行比较,单段式纳米棒样品是在与两段式样品的第一个均匀纳米棒段相似的条件下制备的。两段式样品的所有CL、PL和EL光谱(峰值在520至525纳米之间)在波长上比单段式样品的光谱(峰值在490纳米左右)红移超过30纳米。此外,两段式样品的发射光谱宽度比单段式样品的发射光谱宽度显著增大。PL光谱的半高宽从约37纳米增加到约61纳米。这种变化归因于两段式样品侧壁量子阱中铟的掺入量更高,这是由于横截面尺寸较小的纳米棒段中应变弛豫更强,以及相邻纳米棒之间较大间隙体积提供了更多的组成原子。