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新型生物吸附剂对水溶液中镉(Cd(2+))去除的优化

Optimization of Cadmium (CD(2+)) removal from aqueous solutions by novel biosorbent.

作者信息

Mahmoud Alaa El Din, Fawzy Manal, Radwan Ahmed

机构信息

a Environmental Sciences Department , Faculty of Science, Alexandria University , Alexandria , Egypt.

b Physical Oceanography Department , National Institute of Oceanography and Fisheries , Alexandria , Egypt.

出版信息

Int J Phytoremediation. 2016;18(6):619-25. doi: 10.1080/15226514.2015.1086305.

Abstract

In this research, dead leaves of a common ornamental plant, Dracaena draca known also as dragon tree was used as a biosorbent for the removal of Cadmium (Cd(2+)) from aqueous solutions using a full 2(3) factorial experimental design. Three factors were investigated at two different levels, metal ion concentration (X = 10 and 100 ppm), hydrogen ion concentration (Ph = 2 and 7) and biomass dose (BD = 0.1 and 0.5g). Experiments were carried out in duplicates with 50 ml of Cd(2+) solutions at room temperature. When comparing observed values (experimental) with calculated values (model), they were set closely together that allowed suggesting a normal distribution where (R(2) = 0.9938). A characterization of the biosorbent was done by pHzpc and SEM-EDAX. Results also showed that the most significant effect for Cd(2+) biosorption was ascribed to (X). The interaction effects of (pH BD) and (X pH) were found to have significant influence on Cd(2+) removal efficiency. The highest Cd(2+) removal percentage attained by 79.60% at X = 10 ppm, pH = 7 and BD = 0.5g. The reusability of the biosorbent was tested in three desorption cycles and the regeneration efficiency was above 99.7%.

摘要

在本研究中,一种常见的观赏植物——龙血树(Dracaena draca)的枯叶被用作生物吸附剂,采用全2(3)析因实验设计从水溶液中去除镉(Cd(2+))。研究了三个因素,每个因素设置两个不同水平,分别为金属离子浓度(X = 10和100 ppm)、氢离子浓度(pH = 2和7)以及生物量剂量(BD = 0.1和0.5 g)。实验在室温下对50 ml的Cd(2+)溶液进行了重复操作。将观测值(实验值)与计算值(模型值)进行比较时,发现二者非常接近,表明呈正态分布(R(2) = 0.9938)。通过零电荷点(pHzpc)和扫描电子显微镜-能谱仪(SEM-EDAX)对生物吸附剂进行了表征。结果还表明,对Cd(2+)生物吸附影响最显著的因素是(X)。发现(pH BD)和(X pH)的交互作用对Cd(2+)去除效率有显著影响。在X = 10 ppm、pH = 7和BD = 0.5 g时,Cd(2+)去除率最高达到79.60%。对生物吸附剂的可重复使用性进行了三个解吸循环的测试,再生效率高于99.7%。

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