Smectic Gardening on Curved Landscapes.

Focal conic domains (FCDs) form in smectic-A liquid crystal films with hybrid anchoring conditions with eccentricity and size distribution that depend strongly on interface curvature. Assemblies of FCDs can be exploited in settings ranging from optics to material assembly. Here, using micropost arrays with different shapes and arrangement, we assemble arrays of smectic flower patterns, revealing their internal structure as well as defect size, location, and distribution as a function of interface curvature, by imposing positive, negative, or zero Gaussian curvature at the free surface. We characterize these structures, relating free surface topography, substrate anchoring strength, and FCD distribution. Whereas the largest FCDs are located in the thickest regions of the films, the distribution of sizes is not trivially related to height, due to Apollonian tiling. Finally, we mold FCDs around microposts of complex shape and find that FCD arrangements are perturbed near the posts, but are qualitatively similar far from the posts where the details of the confining walls and associated curvature fields decay. This ability to mold FCD defects into a variety of hierarchical assemblies by manipulating the interface curvature paves the way to create new optical devices, such as compound eyes, via a directed assembly scheme.