Sánchez-Ferrer Antoni, Carney Randy P, Stellacci Francesco, Mezzenga Raffaele, Isa Lucio
Laboratory of Food and Soft Matter, Department of Health Sciences and Technology, ETH Zurich , Schmelzbergstrasse 9, CH-8092 Zurich, Switzerland.
Institute of Materials, Ecole Polytechnique Fédérale de Lausanne , CH-1015 Lausanne, Switzerland.
Langmuir. 2015 Oct 20;31(41):11179-85. doi: 10.1021/acs.langmuir.5b01811. Epub 2015 Oct 6.
Monodispersity is a key property to control the self-assembly of colloidal particles, and is typically reached after fine-tuning of the synthesis conditions. Monodisperse particle fractions can also be separated from polydisperse suspensions via ultracentrifugation. This paper demonstrates the capability of isolating and characterizing suspensions of core-shell iron oxide-polymer nanoparticles with extremely low polydispersity (p < 0.01) and, thus, of complementing nanoparticle synthetic approaches in the pursuit of highly monodisperse materials.