Treatment of industrial effluents by electrochemical generation of H2O2 using an RVC cathode in a parallel plate reactor.

Electrochemical techniques have been used for the discolouration of synthetic textile industrial wastewater by Fenton's process using a parallel plate reactor with a reticulated vitreous carbon (RVC) cathode. It has been shown that RVC is capable of electro-generating and activating H2O2 in the presence of Fe(2+) added as catalyst and using a stainless steel mesh as anode material. A catholyte comprising 0.05 M Na2SO4, 0.001 M FeSO4.7H2O, 0.01 M H2SO4 and fed with oxygen was used to activate H2O2.The anolyte contained only 0.8 M H2SO4. The operating experimental conditions were 170 mA (2.0 V < ΔECell < 3.0 V) to generate 5.3 mM H2O2. Synthetic effluents containing various concentrations (millimolar - mM) of three different dyes, Blue Basic 9 (BB9), Reactive Black 5 (RB5) and Acid Orange 7 (AO7), were evaluated for discolouration using the electro-assisted Fenton reaction. Water discolouration was measured by UV-VIS absorbance reduction. Dye removal by electrolysis was a function of time: 90% discolouration of 0.08, 0.04 and 0.02 mM BB9 was obtained at 14, 10 and 6 min, respectively. In the same way, 90% discolouration of 0.063, 0.031 and 0.016 mM RB5 was achieved at 90, 60 and 30 min, respectively. Finally, 90% discolouration of 0.14, 0.07 and 0.035 mM AO7 was achieved at 70, 40 and 20 min, respectively. The experimental results confirmed the effectiveness of electro-assisted Fenton reaction as a strong oxidizing process in water discolouration and the ability of RVC cathode to electro-generate and activate H2O2 in situ.