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用于基于聚合物电解质的固态染料敏化太阳能电池的聚(3,4-乙撑二氧噻吩)-b-聚乙二醇嵌段共聚物对电极具有优异的光学和界面性能。

Excellent optical and interfacial performance of a PEDOT-b-PEG block copolymer counter electrode for polymer electrolyte-based solid-state dye-sensitized solar cells.

作者信息

Kim Tea-Yon, Wei Wei, Cho Woohyung, Lee Sungjin, Won Jongok, Kang Yong Soo

机构信息

Department of Energy Engineering and Center for Next-Generation Dye-Sensitized Solar Cells, Hanyang University, Seoul 133-791, Korea.

Department of Chemistry, Sejong Polymer Research Center, Sejong University, 209, Neungdong-ro, Gwangjin-gu, Seoul 143-747, Korea.

出版信息

Chem Commun (Camb). 2015 Dec 7;51(94):16782-5. doi: 10.1039/c5cc06546a.

Abstract

A poly(3,4-ethylenedioxythiophene)-b-poly(ethylene glycol) (PEDOT-b-PEG) block copolymer doped with perchlorate on FTO shows excellent optical and interfacial performance as a counter electrode (CE), such as low charge transfer resistance and low reflectivity for polymer electrolyte-based solid-state dye-sensitized solar cells (DSCs), resulting in 8.45% energy conversion efficiency, greater than the common Pt CE, via a facile room-temperature process.

摘要

在氟掺杂氧化锡(FTO)上掺杂高氯酸盐的聚(3,4-乙撑二氧噻吩)-b-聚(乙二醇)(PEDOT-b-PEG)嵌段共聚物作为对电极(CE)表现出优异的光学和界面性能,例如对于基于聚合物电解质的固态染料敏化太阳能电池(DSC)具有低电荷转移电阻和低反射率,通过简便的室温工艺,其能量转换效率达到8.45%,高于普通的铂对电极。

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