Youn Yong, Han Seungwu
Department of materials Science and Engineering and Research Institute of Advanced Materials, Seoul National University, Seoul 151-744, Korea.
Phys Chem Chem Phys. 2015 Nov 7;17(41):27806-11. doi: 10.1039/c5cp03125g.
In order to calculate ion currents through solid-state nanopore transistors realistically, we propose a computational model based on the Poisson-Nernst-Plank equation. In the present model, we determine the surface charge density locally on the nanopore by imposing consistency between the ion distribution and the chemical reaction at the surface. The model can consider a non-uniform influence by the gate voltage on the inner surface of the nanopore membrane, which enables us to investigate ion currents depending on the gate geometry such as the thickness and vertical position within the nanopore. We verify the validity of the model by comparing the pH dependence of simulation results with the extant experimental results. We also investigate the transistor behaviour depending on the surface material, pore geometry and gate position. In particular, we propose an optimized system to enhance the on/off ratio of the nanopore transistor.
为了实际计算通过固态纳米孔晶体管的离子电流,我们提出了一种基于泊松 - 能斯特 - 普朗克方程的计算模型。在当前模型中,我们通过使离子分布与表面化学反应保持一致来局部确定纳米孔上的表面电荷密度。该模型可以考虑栅极电压对纳米孔膜内表面的非均匀影响,这使我们能够研究取决于栅极几何形状(如纳米孔内的厚度和垂直位置)的离子电流。我们通过将模拟结果的pH依赖性与现有实验结果进行比较来验证模型的有效性。我们还研究了取决于表面材料、孔几何形状和栅极位置的晶体管行为。特别是,我们提出了一种优化系统来提高纳米孔晶体管的开/关比。