• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Na5[Mn(l-酒石酸)2]·12H2O（l-酒石酸=l-酒石酸盐）的高压晶体学和磁性研究

A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate).

作者信息

Craig Gavin A, Woodall Christopher H, McKellar Scott C, Probert Michael R, Kamenev Konstantin V, Moggach Stephen A, Brechin Euan K, Parsons Simon, Murrie Mark

机构信息

WestCHEM, School of Chemistry, University of Glasgow, Glasgow, G12 8QQ, UK.

出版信息

Dalton Trans. 2015 Nov 14;44(42):18324-8. doi: 10.1039/c5dt03320a. Epub 2015 Oct 8.

DOI:10.1039/c5dt03320a
PMID:26447366
Abstract

The crystal structure and magnetic properties of the compound Na5[Mn(l-tart)2]·12H2O (1, l-tart = l-tartrate) have been investigated over the pressure range 0.34-3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na(+) ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.

摘要

已在0.34 - 3.49吉帕的压力范围内研究了化合物Na5[Mn(l - 酒石酸)2]·12H2O（1，l - 酒石酸 = 左旋酒石酸盐）的晶体结构和磁性。已确定1的体积模量为23.9(6)吉帕，观察到Na(+)离子周围的配位球发生了压缩。因此，1相对不可压缩，这有助于它在压力下保持其磁各向异性。

相似文献

1
A high-pressure crystallographic and magnetic study of Na5[Mn(l-tart)2]·12H2O (l-tart = l-tartrate).Na5[Mn(l-酒石酸)2]·12H2O（l-酒石酸=l-酒石酸盐）的高压晶体学和磁性研究
Dalton Trans. 2015 Nov 14;44(42):18324-8. doi: 10.1039/c5dt03320a. Epub 2015 Oct 8.
2
Field-induced slow relaxation in a monometallic manganese(III) single-molecule magnet.单金属锰（III）单分子磁体中的场致慢弛豫
Inorg Chem. 2015 Jan 5;54(1):13-5. doi: 10.1021/ic5024136. Epub 2014 Dec 12.
3
Vanadium(V) tartrato complexes: speciation in the H3O+(OH-)/H2VO4-/(2R,3R)-tartrate system and X-ray crystal structures of Na4[V4O8(rac-tart)2].12H2O and (NEt4)4[V4O8((R,R)-tart)2].6H2O (tart = C4H2O6(4-)).钒（V）酒石酸配合物：H3O+(OH-)/H2VO4-/(2R,3R)-酒石酸体系中的物种形成以及Na4[V4O8(rac-酒石酸)2].12H2O和(NEt4)4[V4O8((R,R)-酒石酸)2].6H2O（酒石酸 = C4H2O6(4-)）的X射线晶体结构
Inorg Chem. 2007 May 14;46(10):3971-83. doi: 10.1021/ic062223h. Epub 2007 Apr 10.
4
Chiral molecular magnets: synthesis, structure, and magnetic behavior of the series [M(L-tart)] (M = Mn(II), Fe(II), Co(II), Ni(II); L-tart = (2R,3R)-(+)-tartrate).手性分子磁体：[M(L-酒石酸)]系列（M = Mn(II)、Fe(II)、Co(II)、Ni(II)；L-酒石酸 = (2R,3R)-(+)-酒石酸盐）的合成、结构及磁行为
Chemistry. 2006 Apr 24;12(13):3484-92. doi: 10.1002/chem.200501351.
5
A chiral molecular conductor: synthesis, structure, and physical properties of [ET]3[Sb2(L-tart)2].CH3CN (ET = bis(ethylendithio)tetrathiafulvalene; L-tart = (2R,3R)-(+)-tartrate).一种手性分子导体：[ET]3[Sb2(L - 酒石酸)2].CH3CN的合成、结构及物理性质（ET = 双(亚乙基二硫代)四硫富瓦烯；L - 酒石酸 = (2R,3R)-(+)-酒石酸盐）
Inorg Chem. 2004 Dec 13;43(25):8072-7. doi: 10.1021/ic049257e.
6
Stereospecific formation of dinuclear vanadium(V) tartrato complexes.双核钒（V）酒石酸络合物的立体定向形成
Inorg Chem. 2009 Sep 7;48(17):8423-30. doi: 10.1021/ic901024p.
7
Structure and magnetic properties of the two-dimensional ferrimagnet (NEt4)[[Mn(salen)]2Fe(CN)6]: investigation of magnetic anisotropy on a single crystal.二维铁磁体(NEt4)[[Mn(salen)]2Fe(CN)6]的结构与磁性：单晶磁各向异性研究
Inorg Chem. 2003 Jun 2;42(11):3509-15. doi: 10.1021/ic026261m.
8
Synthesis and Structure of High-Nuclearity Carboxylate-Modified Heteropolyoxovanadate Serving as a Heterogeneous Catalyst for Selective Oxidation of Alkylbenzenes.作为烷基苯选择性氧化多相催化剂的高核羧酸盐修饰杂多钒酸盐的合成与结构
Inorg Chem. 2023 Nov 13;62(45):18384-18390. doi: 10.1021/acs.inorgchem.3c01802. Epub 2023 Oct 31.
9
Studies on the association of 2-thiazolidinecarboxylic acid and antimony potassium tartrate: chiral recognition and prediction of absolute configuration by electrospray ionization mass spectrometry.2-噻唑烷羧酸与酒石酸锑钾的关联研究：通过电喷雾电离质谱法进行手性识别和绝对构型预测
Rapid Commun Mass Spectrom. 2001;15(9):685-9. doi: 10.1002/rcm.286.
10
Heteronuclear, mixed-metal Ag(I)-Mn(II) coordination polymers with bridging N-pyridinylisonicotinohydrazide ligands: synthesis, crystal structures, magnetic and photoluminescence properties.具有桥连N-吡啶基异烟酰肼配体的异核混合金属Ag(I)-Mn(II)配位聚合物：合成、晶体结构、磁性和光致发光性质
Dalton Trans. 2014 Aug 21;43(31):11925-35. doi: 10.1039/c4dt01390e.

引用本文的文献

1
Behavior of Occupied and Void Space in Molecular Crystal Structures at High Pressure.高压下分子晶体结构中占据空间与空穴空间的行为
Cryst Growth Des. 2022 Apr 6;22(4):2328-2341. doi: 10.1021/acs.cgd.1c01427. Epub 2022 Mar 22.
2
Probing the origin of the giant magnetic anisotropy in trigonal bipyramidal Ni(ii) under high pressure.高压下三角双锥镍（II）中巨磁各向异性起源的探究
Chem Sci. 2017 Dec 19;9(6):1551-1559. doi: 10.1039/c7sc04460g. eCollection 2018 Feb 14.