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随机钉扎改变了二维核心软化势系统的熔化情形。

Random pinning changes the melting scenario of a two-dimensional core-softened potential system.

作者信息

Tsiok E N, Dudalov D E, Fomin Yu D, Ryzhov V N

机构信息

Institute for High Pressure Physics RAS, Kaluzhskoe shosse 14, 142190 Troitsk, Moscow, Russia.

Moscow Institute of Physics and Technology, 141700 Moscow, Russia.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2015 Sep;92(3):032110. doi: 10.1103/PhysRevE.92.032110. Epub 2015 Sep 8.

DOI:10.1103/PhysRevE.92.032110
PMID:26465429
Abstract

In experiments two-dimensional systems are realized mainly on solid substrates, which introduce quenched disorder due to some inherent defects. The defects of substrates influence the melting scenario of the systems and have to be taken into account in the interpretation of experimental results. We present the results of molecular dynamics simulations of a two-dimensional system with a core-softened potential in which a small fraction of the particles is pinned, inducing quenched disorder. Ppotentials of this type are widely used for the qualitative description of systems with waterlike anomalies. In our previous publications it was shown that the system demonstrates an anomalous melting scenario: at low densities the system melts through two continuous transitions in accordance with the Kosterlitz-Thouless-Halperin-Nelson-Young (KTHNY) theory with an intermediate hexatic phase, while at high densities the conventional first-order melting transition takes place. We find that the well-known disorder-induced widening of the hexatic phase occurs at low densities, while in the high-density part of the phase diagram random pinning transforms the first-order melting into two transitions: a continuous KTHNY-like solid-hexatic transition and a first-order hexatic-isotropic liquid transition.

摘要

在实验中,二维系统主要在固体衬底上实现,这些衬底由于一些固有缺陷会引入淬火无序。衬底的缺陷会影响系统的熔化情况,在解释实验结果时必须予以考虑。我们展示了一个具有核心软化势的二维系统的分子动力学模拟结果,其中一小部分粒子被固定,从而引发淬火无序。这种类型的势广泛用于对具有类似水异常的系统进行定性描述。在我们之前的出版物中表明,该系统呈现出一种异常的熔化情况:在低密度下,系统根据科斯特利茨 - Thouless - 哈珀林 - 尼尔森 - 杨(KTHNY)理论通过两个连续转变熔化,中间存在一个六方相,而在高密度下则发生常规的一级熔化转变。我们发现,在低密度下会出现众所周知的由无序导致的六方相展宽,而在相图的高密度部分,随机钉扎将一级熔化转变为两个转变:一个类似KTHNY的连续固 - 六方转变和一个一级六方 - 各向同性液体转变。

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