具有磁有序性的柱状三维配位聚合物的无溶剂合成
Solvent-Free Synthesis of a Pillared Three-Dimensional Coordination Polymer with Magnetic Ordering.
作者信息
López-Cabrelles Javier, Giménez-Marqués Mónica, Mínguez Espallargas Guillermo, Coronado Eugenio
机构信息
Instituto de Ciencia Molecular (ICMol), Universidad de Valencia , c/Catedrático José Beltrán, 2, 46980 Paterna, Spain.
Institut Lavoisier CNRS UMR 8180, Université de Versailles St Quentin-en-Yvelines , 45, Avenue des Etats Unis, 78035 Versailles Cedex, France.
出版信息
Inorg Chem. 2015 Nov 2;54(21):10490-6. doi: 10.1021/acs.inorgchem.5b02003. Epub 2015 Oct 15.
A new magnetic coordination polymer, [Fe(bipy)(im)2] (bipy = 4,4-bipyridine and im = imidazole), has been synthesized in a solvent-free reaction. Structural analysis reveals a pillared 3D coordination polymer composed by neutral layers, formed by iron(II) and imidazolate linkers, interconnected by bipy ligands which serve as pillars. Magnetic measurements show that the material magnetically orders at low temperatures (Tc = 14.5 K) as a weak ferromagnet, likely due to a spin canting.
一种新型磁性配位聚合物[Fe(bipy)(im)₂]（bipy = 4,4-联吡啶，im = 咪唑）已在无溶剂反应中合成。结构分析表明，它是一种柱状三维配位聚合物，由中性层组成，这些中性层由铁（II）和咪唑盐连接体形成，通过充当支柱的联吡啶配体相互连接。磁性测量表明，该材料在低温下（Tc = 14.5 K）呈现弱铁磁有序，这可能是由于自旋倾斜所致。
Zotero 插件