负载于氮掺杂多孔碳上的镍用于在硫酸中将硝基苯加氢制备对氨基苯酚。
Nickel embedded in N-doped porous carbon for the hydrogenation of nitrobenzene to p-aminophenol in sulphuric acid.
作者信息
Wang Tao, Dong Zhen, Fu Teng, Zhao Yanchao, Wang Tian, Wang Yongzheng, Chen Yi, Han Baohang, Ding Weiping
机构信息
Key Lab of Mesoscopic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
National Center for Nanoscience and Technology, Beijing 100190, China.
出版信息
Chem Commun (Camb). 2015 Dec 28;51(100):17712-5. doi: 10.1039/c5cc06268c.
An acid-resistant catalyst composed of nickel embedded in N-doped porous carbon is developed for the catalytic hydrogenation of nitrobenzene (NB) to p-aminophenol (PAP). The catalyst, due to a special electron donation from nickel to the N-doped porous carbon, shows an excellent catalytic performance and stability in sulphuric acid solution.
一种由嵌入氮掺杂多孔碳中的镍组成的耐酸催化剂被开发用于将硝基苯（NB）催化氢化为对氨基苯酚（PAP）。由于镍向氮掺杂多孔碳的特殊电子给予作用，该催化剂在硫酸溶液中表现出优异的催化性能和稳定性。
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