Department of Environmental and Occupational Health, School of Public Health, Texas A&M University, College Station, TX 77843, USA.
Department of Environmental and Occupational Health, School of Public Health, Texas A&M University, College Station, TX 77843, USA.
Adv Colloid Interface Sci. 2015 Nov;225:229-40. doi: 10.1016/j.cis.2015.10.006. Epub 2015 Oct 22.
One of the biggest challenges of the 21st century is to provide clean and affordable water through protecting source and purifying polluted waters. This review presents advances made in the synthesis of carbon- and iron-based nanomaterials, graphene-carbon nanotubes-iron oxides, which can remove pollutants and inactivate virus and bacteria efficiently in water. The three-dimensional graphene and graphene oxide based nanostructures exhibit large surface area and sorption sites that provide higher adsorption capacity to remove pollutants than two-dimensional graphene-based adsorbents and other conventional adsorbents. Examples are presented to demonstrate removal of metals (e.g., Cu, Pb, Cr(VI), and As) and organics (e.g., dyes and oil) by grapheme-based nanostructures. Inactivation of Gram-positive and Gram-negative bacterial species (e.g., Escherichia coli and Staphylococcus aureus) is also shown. A mechanism involving the interaction of adsorbents and pollutants is briefly discussed. Magnetic graphene-based nanomaterials can easily be separated from the treated water using an external magnet; however, there are challenges in implementing the graphene-based nanotechnology in treating real water.
二十一世纪最大的挑战之一是通过保护水源和净化受污染的水来提供清洁和负担得起的水。本篇综述介绍了在合成碳基和铁基纳米材料方面的进展,即石墨烯-碳纳米管-氧化铁,它可以有效地去除水中的污染物、灭活病毒和细菌。三维石墨烯和基于氧化石墨烯的纳米结构具有较大的表面积和吸附位点,比二维基于石墨烯的吸附剂和其他传统吸附剂具有更高的吸附容量来去除污染物。实例证明了基于石墨烯的纳米结构可以去除金属(例如 Cu、Pb、Cr(VI) 和 As)和有机物(例如染料和油)。还展示了对革兰氏阳性和革兰氏阴性细菌物种(例如大肠杆菌和金黄色葡萄球菌)的灭活。简要讨论了涉及吸附剂和污染物相互作用的机制。基于磁性石墨烯的纳米材料可以很容易地使用外部磁铁从处理过的水中分离出来;然而,在实际水处理中实施基于石墨烯的纳米技术存在挑战。