Yao Jun, Yang Mei, Liu Yu, Duan Yixiang
J Nanosci Nanotechnol. 2015 May;15(5):3720-7. doi: 10.1166/jnn.2015.9522.
CdS quantum dot (QD) is a typical kind of II-IV nanoparticles, which plays an important role in the common type of core-shell QDs. It is of great practical significance to synthesize the water-soluble CdS QDs used in multicolor biomarkers and prepare core-shell QDs. In our case, we came up with a novel green method to manufacture CdS QDs with high quality, different size, and adopted UV-vis absorption, fluorescence, FTIR, XPS, HRTEM, SAED and STEM-EDX to discuss their growth mechanism. We successfully constructed fluorescence resonance energy transfer (FRET) system between CdS QDs and gold nanoparticles (AuNPs), then comprehensively and systematically studied the interaction between them.
硫化镉量子点(QD)是典型的II-IV族纳米颗粒,在常见的核壳量子点类型中起着重要作用。合成用于多色生物标志物的水溶性硫化镉量子点并制备核壳量子点具有重大的实际意义。在我们的研究中,我们提出了一种新颖的绿色方法来制造高质量、不同尺寸的硫化镉量子点,并采用紫外可见吸收光谱、荧光光谱、傅里叶变换红外光谱、X射线光电子能谱、高分辨率透射电子显微镜、选区电子衍射和扫描透射电子显微镜-能谱仪来探讨其生长机制。我们成功构建了硫化镉量子点与金纳米颗粒(AuNP)之间的荧光共振能量转移(FRET)系统,然后全面系统地研究了它们之间的相互作用。