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随机热力学中的涨落电流。I. 渐近统计的规范不变性。

Fluctuating currents in stochastic thermodynamics. I. Gauge invariance of asymptotic statistics.

作者信息

Wachtel Artur, Vollmer Jürgen, Altaner Bernhard

机构信息

Department of Dynamics of Complex Fluids (DCF), Max Planck Institute for Dynamics and Self-Organization (MPI DS), Am Fassberg 17, 37077 Göttingen, Germany and Institute for Nonlinear Dynamics, Faculty of Physics, Georg-August University Göttingen, 37077 Göttingen, Germany.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2015 Oct;92(4):042132. doi: 10.1103/PhysRevE.92.042132. Epub 2015 Oct 14.

Abstract

Stochastic thermodynamics uses Markovian jump processes to model random transitions between observable mesoscopic states. Physical currents are obtained from antisymmetric jump observables defined on the edges of the graph representing the network of states. The asymptotic statistics of such currents are characterized by scaled cumulants. In the present work, we use the algebraic and topological structure of Markovian models to prove a gauge invariance of the scaled cumulant-generating function. Exploiting this invariance yields an efficient algorithm for practical calculations of asymptotic averages and correlation integrals. We discuss how our approach generalizes the Schnakenberg decomposition of the average entropy-production rate, and how it unifies previous work. The application of our results to concrete models is presented in an accompanying publication.

摘要

随机热力学使用马尔可夫跳跃过程来对可观测介观态之间的随机跃迁进行建模。物理电流是从定义在表示态网络的图的边上的反对称跳跃可观测量中获得的。此类电流的渐近统计特性由标度累积量来表征。在本工作中,我们利用马尔可夫模型的代数和拓扑结构来证明标度累积量生成函数的规范不变性。利用这种不变性可得到一种用于渐近平均值和相关积分实际计算的高效算法。我们讨论了我们的方法如何推广平均熵产生率的施纳肯贝格分解,以及它如何统一先前的工作。我们的结果在一篇配套出版物中展示了其在具体模型中的应用。

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