Zhu Yuan-Yuan, Liu Chang-Wei, Yin Ji, Meng Zhao-Sha, Yang Qian, Wang Junhu, Liu Tao, Gao Song
School of Chemistry and Chemical Engineering, Hefei University of Technology and Anhui Key Laboratory of Advanced Functional Materials and Devices, Hefei 230009, China.
Dalton Trans. 2015 Dec 28;44(48):20906-12. doi: 10.1039/c5dt03216d. Epub 2015 Nov 17.
Herein, we report the investigation of a mononuclear spin-crossover complex [Fe(II)L2][ClO4]2 (L = 2,6-bis{4,4-dimethyl-4,5-dihydrooxazol-2-yl}pyridine). This compound undergoes a structural phase transition around 173 K, accompanying with an abrupt spin-transition process. Interestingly, it exhibits a multi-induced spin-crossover behavior mediated by heat, light, pressure and solvent.
在此，我们报道了对单核自旋交叉配合物[Fe(II)L2][ClO4]2（L = 2,6-双{4,4-二甲基-4,5-二氢恶唑-2-基}吡啶）的研究。该化合物在173 K左右经历结构相变，并伴随着一个突然的自旋转变过程。有趣的是，它表现出由热、光、压力和溶剂介导的多诱导自旋交叉行为。
