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通过NDMP阴离子交换工艺去除生物处理后的纺织废水中的荧光溶解性有机物:效率与机制

Removal of fluorescent dissolved organic matter in biologically treated textile effluents by NDMP anion exchange process: efficiency and mechanism.

作者信息

Li Wen-Tao, Xu Zi-Xiao, Shuang Chen-Dong, Zhou Qing, Li Hai-Bo, Li Ai-Min

机构信息

State Key Laboratory of Pollution Control and Resources Reuse, Collaborative Innovation Center for Advanced Water Pollution Control Technology and Equipment, School of the Environment, Nanjing University, Nanjing, 210023, China.

出版信息

Environ Sci Pollut Res Int. 2016 Mar;23(6):5635-43. doi: 10.1007/s11356-015-5492-5. Epub 2015 Nov 18.

Abstract

The efficiency and mechanism of anion exchange resin Nanda Magnetic Polymer (NDMP) for removal of fluorescent dissolved organic matter in biologically treated textile effluents were studied. The bench-scale experiments showed that as well as activated carbon, anion exchange resin could efficiently remove both aniline-like and humic-like fluorescent components, which can be up to 40 % of dissolved organic matter. The humic-like fluorescent component HS-Em460-Ex3 was more hydrophilic than HS-Em430-Ex2 and contained fewer alkyl chains but more acid groups. As a result, HS-Em460-Ex3 was eliminated more preferentially by NDMP anion exchange. However, compared with adsorption resins, the polarity of fluorescent components had a relatively small effect on the performance of anion exchange resin. The long-term pilot-scale experiments showed that the NDMP anion exchange process could remove approximately 30 % of the chemical oxygen demand and about 90 % of color from the biologically treated textile effluents. Once the issue of waste brine from resin desorption is solved, the NDMP anion exchange process could be a promising alternative for the advanced treatment of textile effluents.

摘要

研究了阴离子交换树脂南达磁性聚合物(NDMP)去除生物处理后纺织废水中荧光溶解性有机物的效率和机制。实验室规模实验表明,与活性炭一样,阴离子交换树脂能有效去除类苯胺和类腐殖质荧光成分,其去除率可达溶解性有机物的40%。类腐殖质荧光成分HS-Em460-Ex3比HS-Em430-Ex2亲水性更强,烷基链更少但酸性基团更多。因此,HS-Em460-Ex3更优先被NDMP阴离子交换去除。然而,与吸附树脂相比,荧光成分的极性对阴离子交换树脂性能的影响相对较小。长期中试规模实验表明,NDMP阴离子交换工艺可去除生物处理后纺织废水中约30%的化学需氧量和约90%的色度。一旦解决树脂解吸产生的废盐水问题,NDMP阴离子交换工艺有望成为纺织废水深度处理的替代方法。

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