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[三峡库区长寿湖水体中不同形态汞的空间分布特征]

[Spatial Distribution Characteristics of Different Species Mercury in Water Body of Changshou Lake in Three Gorges Reservoir Region].

作者信息

Bai Wei-yang, Zhang Cheng, Zhao Zheng, Tang Zhen-ya, Wang Ding-yong

出版信息

Huan Jing Ke Xue. 2015 Aug;36(8):2863-9.

Abstract

An investigation on the concentrations and the spatial distribution characteristics of different species of mercury in the water body of Changshou Lake in Three Gorges Reservoir region was carried out based on the AreGIS statistics module. The results showed that the concentration of the total mercury in Changshou Lake surface water ranged from 0.50 to 3.78 ng x L(-1), with an average of 1.51 ng x L(-1); the concentration of the total MeHg (methylmercury) ranged from 0.10 to 0.75 ng x L(-1), with an average of 0.23 ng x L(-1). The nugget effect value of total mercury in surface water (50.65%), dissolved mercury (49.80%), particulate mercury (29.94%) and the activity mercury (26.95%) were moderate spatial autocorrelation. It indicated that the autocorrelation was impacted by the intrinsic properties of sediments (such as parent materials and rocks, geological mineral and terrain), and on the other hand it was also disturbed by the exogenous input factors (such as aquaculture, industrial activities, farming etc). The nugget effect value of dissolved methylmercury (DMeHg) in Changshou lake surface water (3.49%) was less than 25%, showing significant strong spatial autocorrelation. The distribution was mainly controlled by environmental factors in water. The proportion of total MeHg in total Hg in Changshou Lake water reached 30% which was the maximum ratio of the total MeHg to total Hg in freshwater lakes and rivers. It implied that mercury was easily methylated in the environment of Chanashou Lake.

摘要

基于ArcGIS统计模块,对三峡库区长寿湖水体中不同形态汞的含量及空间分布特征进行了调查。结果表明,长寿湖表层水中总汞浓度范围为0.503.78 ng·L-1,平均为1.51 ng·L-1;总甲基汞(MeHg)浓度范围为0.100.75 ng·L-1,平均为0.23 ng·L-1。表层水中总汞(50.65%)、溶解态汞(49.80%)、颗粒态汞(29.94%)和活性汞(26.95%)的块金效应值具有中等空间自相关性。这表明自相关性一方面受沉积物内在性质(如母质和岩石、地质矿物和地形)的影响,另一方面也受到外源输入因素(如水产养殖、工业活动、农业等)的干扰。长寿湖表层水中溶解态甲基汞(DMeHg)的块金效应值(3.49%)小于25%,表现出显著的强空间自相关性。其分布主要受水体环境因素控制。长寿湖水中总MeHg占总Hg的比例达30%,是淡水湖泊和河流中总MeHg与总Hg的最大比值。这意味着汞在长寿湖环境中易于甲基化。

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