Yu Yang, Ma Jian-Ping, Zhao Chao-Wei, Yang Jing, Zhang Xiao-Meng, Liu Qi-Kui, Dong Yu-Bin
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University , Jinan 250014, P. R. China.
Inorg Chem. 2015 Dec 21;54(24):11590-2. doi: 10.1021/acs.inorgchem.5b02150. Epub 2015 Dec 8.
A porous Cu(I)-MOF [H2O⊂Cu2(L)2I2; L = 1-benzimidazolyl-3,5-bis(4-pyridyl)benzene], which can be a visual and luminescent sensor for detecting small polar aliphatic volatile organic compounds (VOCs), such as alcohols, ketones, and halocarbons, is reported. The naked-eye and luminescent detection limitations for these VOCs are 5 and 1 ppm, respectively.
据报道，一种多孔铜（I）-金属有机框架化合物[H2O⊂Cu2(L)2I2；L = 1-苯并咪唑基-3,5-双（4-吡啶基）苯]，可作为一种可视化发光传感器，用于检测小极性脂肪族挥发性有机化合物（VOCs），如醇类、酮类和卤代烃。这些VOCs的肉眼检测限和发光检测限分别为5 ppm和1 ppm。
