以环重排复分解为关键步骤的螺旋烷衍生物和氧杂碗状化合物的设计与合成。
Design and synthesis of propellane derivatives and oxa-bowls via ring-rearrangement metathesis as a key step.
作者信息
Kotha Sambasivarao, Gunta Rama
机构信息
Department of Chemistry, Indian Institute of Technology-Bombay, Powai, Mumbai-400 076, India.
出版信息
Beilstein J Org Chem. 2015 Sep 24;11:1727-31. doi: 10.3762/bjoc.11.188. eCollection 2015.
Abstract
Various intricate propellane derivatives and oxa-bowls have been synthesized via a ring-rearrangement metathesis (RRM) as a key step starting from readily accessible starting materials such as p-benzoquinone, 1,4-naphthoquinone and 1,4-anthraquinone.
摘要
通过环重排复分解反应（RRM）作为关键步骤，从诸如对苯醌、1,4-萘醌和1,4-蒽醌等易于获得的起始原料出发，已经合成了各种复杂的螺旋烷衍生物和氧杂碗状化合物。
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