降冰片烯衍生物的桥头邻位二烯丙基化反应及通过闭环复分解反应扩展至螺桨烷衍生物
Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis.
作者信息
Kotha Sambasivarao, Gunta Rama
机构信息
Department of Chemistry, Indian Institute of Technology-Bombay, Powai, Mumbai, India.
出版信息
Beilstein J Org Chem. 2016 Aug 22;12:1877-1883. doi: 10.3762/bjoc.12.177. eCollection 2016.
Abstract
Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correction of earlier reported molecules.
摘要
在此，我们报道了一种用于降冰片烯衍生物桥头邻位二烯丙基化反应的简单合成策略。这些底物可用于通过闭环复分解反应生成螺桨烷。对四种化合物的单晶X射线衍射分析实现了对早期报道分子构型的修正。
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