Xu Wen-bin, Chai Lu, Shi Jun-kai, Song You-jian, Hu Ming-lie, Wang Qing-yue, Su Liang-bi, Jiang Da-peng, Xu Jun
Guang Pu Xue Yu Guang Pu Fen Xi. 2015 Sep;35(9):2478-82.
Yb-doped fluoride crystals are of important another Yb-doped laser materials besides Yb-doped oxide, which are becoming one of interests for developing tunable lasers and ultrafast lasers. In this paper, the systematic and contrastive experiments of the optical spectral characteristics are presented for two types of home-made novel Yb-doped fluoride laser crystals, namely, Yb-doped CaF2-SrF2 mixed crystal and co-doped Yb, Y:CaF2 single crystal. The fluorescent features of Yb-doped CaF2-SrF2 mixed crystal and co-doped Yb, Y:CaF2 single crystal are apparently different by the fluorescence experiment. The physical mechanism of these fluorescence spectra were analyzed and proposed. The influence of doping concentrations of active Yb(3+) ions or co-doping Y ions on the absorption of Yb-doped CaF2-SrF2 mixed crystal and co-doped Yb, Y:CaF2 single crystal was experimentally investigated, and the optimal values of doping concentrations of active Yb(3+) ions or co-doping Y ions in the two types of fluoride laser crystals were obtained. Continuous-wave laser operation for the two novel fluoride laser crystals has been achieved in three-mirror-folded resonator using a laser diode as the pump source. Therein, the laser operation for the co-doped Yb, Y:CaF2 crystal is demonstrated for the first time. For the two types of fluoride laser crystals (four samples), the input-output power relational curves, the optical slope efficiencies and the laser spectra were demonstrated by the laser experiments. By comparisons between the two types of fluoride laser crystals in the absorbability, fluorescence and laser spectra, laser threshold and slope efficiency of the continuous-wave laser operation, the results show that the best one of the four samples in spectral and laser characteristics is co-doped 3at%Yb, 6at% Y:CaF2 single crystal, which has an expected potential in the application. The research results provide available references for improving further laser performance of Yb-doped fluoride crystals.
掺镱氟化物晶体是除掺镱氧化物之外的另一类重要的掺镱激光材料,正成为开发可调谐激光器和超快激光器的研究热点之一。本文针对两种国产新型掺镱氟化物激光晶体,即掺镱CaF2-SrF2混合晶体和Yb、Y共掺CaF2单晶,开展了光谱特性的系统对比实验。通过荧光实验发现,掺镱CaF2-SrF2混合晶体和Yb、Y共掺CaF2单晶的荧光特性明显不同。分析并提出了这些荧光光谱的物理机制。实验研究了活性Yb(3+)离子掺杂浓度或Y离子共掺杂对掺镱CaF2-SrF2混合晶体和Yb、Y共掺CaF2单晶吸收的影响,得到了两种氟化物激光晶体中活性Yb(3+)离子掺杂浓度或Y离子共掺杂的最佳值。以激光二极管作为泵浦源,在三镜折叠腔中实现了两种新型氟化物激光晶体的连续波激光运转。其中,Yb、Y共掺CaF2晶体的激光运转为首次报道。通过激光实验给出了两种氟化物激光晶体(四个样品)的输入-输出功率关系曲线、光斜率效率和激光光谱。通过对两种氟化物激光晶体在吸收、荧光和激光光谱、连续波激光运转的激光阈值和斜率效率等方面的比较,结果表明,四个样品中光谱和激光特性最佳的是Yb、Y共掺3at%Yb、6at% Y:CaF2单晶,具有预期的应用潜力。研究结果为进一步提高掺镱氟化物晶体的激光性能提供了参考依据。