Holtzer Mariusz, Dańko Rafał, Kmita Angelika
AGH University of Science and Technology. Faculty of Foundry Engineering, Reymonta 23 street, 30-059 Krakow, Poland.
AGH University of Science and Technology. Academic Centre for Materials and Nanotechnology, al. A. Mickiewicza 30, 30-059 Krakow, Poland.
Water Air Soil Pollut. 2016;227(1):16. doi: 10.1007/s11270-015-2707-9. Epub 2015 Dec 6.
Metalcasting involves having a molten metal poured in a hollow mould to produce metal objects. These moulds are generally made of sand and are chemically bonded, clay-bonded, or even unbounded. There are many binder systems used. Binders based on furfuryl resins constitute currently the highest fraction in the binders no-bake group. Moulding sand, after knocking out the cast, is partially reclaimed, and the remaining part, known as waste foundry sand is used or stored outside the foundry. In this case, the environment hazardous organic compounds and metals can be leached from the moulding sand, thus causing pollution of water and soil. Also during the casting moulds with molten metal, they emit pyrolysis gases containing many different compounds, often dangerous from the BTEX and PAH group, which has adverse impacts on the environment and workers. The article presents the results of research on the impact of the regenerate addition to the moulding sand matrix on emitted gases and the degree of threat to the environment due to leaching of hazardous components. Therefore, for the total assessment of the moulding sands harmfulness, it is necessary to perform investigations concerning the dangerous substances elution into the environment during their management and storage, as well as investigations concerning emissions of hazardous substances (especially from the BTEX and PAHs group) during moulds pouring, cooling, and casting knocking out. Both kinds of investigations indicated that reclaimed sand additions to moulding sands have significantly negative influence on the environment and working conditions.
金属铸造是指将熔融金属倒入中空模具中以生产金属制品。这些模具通常由沙子制成,有化学粘结、粘土粘结甚至无粘结的。使用的粘结剂系统有很多种。基于糠醇树脂的粘结剂目前在自硬粘结剂组中占比最高。铸件脱模后,型砂会部分回收利用,其余部分,即所谓的铸造废砂,会在铸造厂外使用或储存。在这种情况下,环境有害有机化合物和金属会从型砂中浸出,从而造成水和土壤污染。此外,在向铸模中浇注熔融金属时,铸模会释放出含有许多不同化合物的热解气体,这些化合物通常来自苯系物和多环芳烃组,对环境和工人有不利影响。本文介绍了在型砂基体中添加再生料对排放气体的影响以及由于有害成分浸出对环境造成的威胁程度的研究结果。因此,为了全面评估型砂的危害性,有必要对其在管理和储存过程中危险物质向环境中的溶出情况进行调查,以及对铸模浇注、冷却和铸件脱模过程中有害物质(特别是来自苯系物和多环芳烃组的物质)的排放情况进行调查。这两类调查均表明,向型砂中添加再生砂对环境和工作条件有显著负面影响。