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从生态和经济角度看糠醇粘结剂废砂的热再生

Thermal Regeneration of Spent Sand with Furfuryl Binder from an Ecological and Economic Point of View.

作者信息

Łucarz Mariusz, Dereń Michał

机构信息

Faculty of Foundry Engineering, AGH University of Science and Technology, Reymonta 23 St., 30-059 Krakow, Poland.

出版信息

Materials (Basel). 2023 Nov 9;16(22):7102. doi: 10.3390/ma16227102.

Abstract

The recovery of the grain matrix from spent moulding sand is a constant challenge in making the best possible use of the deposits of quartz sand material, as well as in protecting them. In the case of spent sand with organic binders, the best method to recover the grain matrix is thermal regeneration. However, this method is expensive and requires adequate attention to the emission of harmful compounds into the atmosphere. This paper presents a new concept for implementing the thermal regeneration process. A suitable regeneration temperature was adopted for the furfuryl binder moulding sand, and a change in the design of the device was introduced in the area of the utilisation of gases generated during the combustion of the spent binder. To confirm the assumptions made, and to assess the appropriate suitability of the material recovered, the technological parameters of the material obtained were verified, namely, ignition losses, sieve analysis, bending strength, and pH value. The consumption of media for the process was also analysed from an economic point of view, as well as the emission of BTEX (a mixture of volatile aromatic hydrocarbons-benzene, toluene and three isomers of xylene) gases under different conditions of the process. On the basis of the research conducted, it was concluded that lowering the regeneration temperature of regeneration does not adversely affect the technological parameters of the moulding sand on the regenerate matrix. Changing the design of the regenerator does not result in increased emissions of harmful substances to the environment. Studies indicate that the appropriate setting of thermal regeneration parameters and the optimal design of the employed equipment are favourable factors in reducing the cost of the process while not compromising the quality of the moulding sand and the environmental impact.

摘要

从废型砂中回收砂粒基体,对于充分利用石英砂材料储量以及保护这些储量而言,始终是一项挑战。对于含有有机粘结剂的废砂,回收砂粒基体的最佳方法是热再生。然而,这种方法成本高昂,且需要充分关注向大气中排放有害化合物的问题。本文提出了一种实施热再生过程的新概念。针对糠醇粘结剂型砂采用了合适的再生温度,并在废粘结剂燃烧产生的气体利用方面引入了设备设计的变更。为了证实所做的假设,并评估回收材料的适用性,对所得材料的工艺参数进行了验证,即烧失量、筛分分析、抗弯强度和pH值。还从经济角度分析了该过程的介质消耗,以及在不同工艺条件下BTEX(挥发性芳烃混合物——苯、甲苯和三种二甲苯异构体)气体的排放情况。基于所进行的研究得出结论,降低再生温度不会对再生基体上型砂的工艺参数产生不利影响。改变再生器的设计不会导致向环境中排放更多有害物质。研究表明,适当设定热再生参数和对所用设备进行优化设计,是降低该过程成本同时又不影响型砂质量和环境影响的有利因素。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27fc/10672303/915148faa1e6/materials-16-07102-g001.jpg

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