Xiao Jing, Yang Jia, Chen Tieqiao, Han Li-Biao
State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China.
National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan.
Chem Commun (Camb). 2016 Feb 4;52(10):2157-60. doi: 10.1039/c5cc10005d.
An efficient Ni-catalyzed synthesis of (E)-olefins using the readily available benzylic alcohol derivatives and arylacetonitriles is described. This transformation should proceed via a tandem process involving nickel-catalyzed cross coupling via C-O activation and subsequent stereoselective E2 elimination.
描述了一种使用易于获得的苄醇衍生物和芳基乙腈高效镍催化合成（E）-烯烃的方法。这种转化应该通过一个串联过程进行，该过程涉及通过C-O活化的镍催化交叉偶联以及随后的立体选择性E2消除。
