作为反应中间体的金（I）亚乙烯基配合物及其π-反馈键合倾向。
Gold(I) Vinylidene Complexes as Reactive Intermediates and Their Tendency to π-Backbond.
作者信息
Nunes Dos Santos Comprido Laura, Klein Johannes E M N, Knizia Gerald, Kästner Johannes, Hashmi A Stephen K
机构信息
Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.
Department of Chemistry, University of Minnesota, 207 Pleasant St SE, Minneapolis, MN, 55455, USA.
出版信息
Chemistry. 2016 Feb 24;22(9):2892-5. doi: 10.1002/chem.201504511. Epub 2016 Jan 28.
PMID:26711532
Abstract
We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.
摘要
我们在此报告一项关于金（I）亚乙烯基配合物中键合的计算研究，并将它们与其卡宾和一氧化碳类似物进行比较。分析了这些中间体对于导致乙烯基磺酸盐的分子内环化反应的相关性。
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